Mechanistic study on the formation of the alkyl acrylates from CO<sub>2</sub>, ethylene and alkyl iodides over nickel-based catalyst-Reference-Cited by-同舟云学术

Mechanistic study on the formation of the alkyl acrylates from CO₂, ethylene and alkyl iodides over nickel-based catalyst

Published:2023 Issue:36 Volume:25 Page:24733-24744
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhu Youcai¹^ORCID,Mu Yue¹,Sun Li¹^ORCID,Zeng Zuoxiang¹^ORCID,Liu Zhen¹^ORCID

Affiliation:

1. School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

Abstract

The role of methylene linkage on the formation of alkyl acrylate from coupling of CO2/C2H4 is investigated. This work also identifies the non-productive pathways leading to byproducts such as propionic acid, propionates and ion pair complexes, etc.

Funder

Science and Technology Commission of Shanghai Municipality

State Key Laboratory of Chemical Engineering

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP02943C

Reference54 articles.

1. Characteristics of atmospheric CO2 fluxes and the estimation of their potential sources around Boseong Standard Weather Observatory (BSWO)

2. Approach to multi-electron reduction beyond two-electron reduction of CO2

3. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

4. The teraton challenge. A review of fixation and transformation of carbon dioxide

5. Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2

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