Biosynthetic insights provided by unusual sesterterpenes from the medicinal herb Aletris farinosa-Reference-Cited by-同舟云学术

Biosynthetic insights provided by unusual sesterterpenes from the medicinal herb Aletris farinosa

Published:2015 Issue:10 Volume:6 Page:5740-5745
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Challinor Victoria L.¹²³⁴,Johnston Ryne C.¹²³⁴,Bernhardt Paul V.¹²³⁴,Lehmann Reginald P.⁵⁶⁴,Krenske Elizabeth H.¹²³⁴^ORCID,De Voss James J.¹²³⁴

Affiliation:

1. School of Chemistry and Molecular Biosciences

2. The University of Queensland

3. Brisbane 4072

4. Australia

5. Integria Healthcare Pty. Ltd.

6. Brisbane 4133

Abstract

Configuration of a single stereocenter determines if a key carbocation in sesterterpene biosynthesis undergoes simple elimination or a cascade of seven 1,2-methyl and hydride migrations.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02056E

Reference27 articles.

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3. Cyclization of All-E- and 2Z-Geranylfarnesols by a Bacterial Triterpene Synthase: Insight into Sesterterpene Biosynthesis inAleuritopterisFerns

4. Terpenoid synthase structures: a so far incomplete view of complex catalysis

5. J. MacMillan and M. H.Beale , in Comprehensive Natural Products Chemistry , ed. D. E. Cane , Elsevier Science , Oxford , 1999 , vol. 2 , ch. 2.08, pp. 217–243

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