J-aggregation induced emission enhancement of BODIPY dyes via H-bonding directed supramolecular polymerization: the importance of substituents at boron

Author:

Zhang Yongjie1234ORCID,Yuan Siyuan1234,Liu Ping1234,Jing Lei1234,Pan Hongfei1234,Ren Xiang-Kui12345ORCID,Chen Zhijian12345ORCID

Affiliation:

1. School of Chemical Engineering and Technology

2. Tianjin University

3. Tianjin

4. China

5. Collaborative Innovation Center of Chemical Science and Chemical Engineering (Tianjin)

Abstract

For uracil-functionalized BODIPY dyes 1a–c, AIEE upon H-bonding directed J-aggregation was observed for the two dyes bearing alkyne groups at boron while the BF2-chelated dye displayed ACQ, indicating the crucial role of the substituents at boron.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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