Metal-free direct alkylation of unfunctionalized allylic/benzylic sp3C–H bonds via photoredox induced radical cation deprotonation
Author:
Affiliation:
1. Department of Chemistry
2. National University of Singapore
3. Republic of Singapore
4. College of Chemistry and Chemical Engineering
5. Taiyuan University of Technology
6. College of Chemistry
7. Beijing Normal University
8. Beijing
9. China
Abstract
An unprecendented direct alkylation of unfunctionalized allylic/benzylic sp3C–H bondsviaphotoredox induced radical cation deprotonation is disclosed.
Funder
Faculty of Science, National University of Singapore
Science and Engineering Research Council, Agency for Science, Technology and Research
Economic Development Board - Singapore
GlaxoSmithKline
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00953D
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