Luminescence and magnetocaloric effect of Ln4 clusters (Ln = Eu, Gd, Tb, Er) bridged by CO32− deriving from the spontaneous fixation of carbon dioxide in the atmosphere-Reference-Cited by-同舟云学术

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Luminescence and magnetocaloric effect of Ln4 clusters (Ln = Eu, Gd, Tb, Er) bridged by CO32− deriving from the spontaneous fixation of carbon dioxide in the atmosphere

Published:2018 Issue:2 Volume:5 Page:394-402
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Chen Hong-Man¹²³⁴⁵,Wang Wen-Min¹²³⁴⁵,Li Xiao-Qin⁶⁷⁸⁹¹⁰,Chu Xiao-Ya¹²³⁴⁵,Nie Yao-Yao¹²³⁴⁵,Liu Zhen¹²³⁴⁵,Huang Shao-Xia¹²³⁴⁵,Shen Hai-Yun¹²³⁴⁵,Cui Jian-Zhong¹²³⁴⁵^ORCID,Gao Hong-Ling¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. National Demonstration Center for Experimental Chemistry & Chemical Engineering Education

3. National Virtual Simulation Experimental Teaching Center for Chemistry & Chemical Engineering Education

4. Tianjin University

5. Tianjin 300072

6. Key Laboratory of Polyoxometalate Science of the Ministry of Education

7. College of Chemistry

8. Northeast Normal University

9. Changchun

10. P. R. China

Abstract

Ln₄ clusters are bridged by CO₃²⁻, deriving from the spontaneous fixation of CO₂. And the Gd₄ complex can show MCE.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QI/C7QI00658F

Reference70 articles.

1. Spontaneous fixation of carbon dioxide in air by a nickel diamine complex: synthesis and characterization of a trinuclear nickel(II) complex with a novel hydrogen bonding system around a carbonate ligand

2. Changing cage structures through inter-ligand repulsions

3. Double-CO32− Centered [CoII5] Wheel and Modeling of Its Magnetic Properties

4. Structural and magnetic properties of oxyquinolinate clusters of cobalt(ii) and manganese(ii) and serendipitous intake of carbonate during synthesis

5. Hexanuclear Dysprosium(III) Compound Incorporating Vertex- and Edge-Sharing Dy3 Triangles Exhibiting Single-Molecule-Magnet Behavior

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5. Two tetranuclear Tb(III)-based clusters: Crystal structures and effectively catalyze the cycloaddition of CO2 with epoxides;Polyhedron;2023-10

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