Stereoselective benzilic acid rearrangements: new advances on an old story

Author:

Burke Anthony J.12345ORCID,Moutayakine Amina67245

Affiliation:

1. LAQV-REQUIMTE

2. University of Évora

3. Institute for Research and Advanced Training (IIFA)

4. Évora

5. Portugal

6. Department of Chemistry

7. School of Science and Technology

Abstract

The benzilic acid rearrangement (BAR) is a powerful method introducing key structural elements in many targets. In this article we discuss important recent stereoselective BARs that include the first enantioselective catalytic example.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference19 articles.

1. B. P. Mundy , M. G.Ellerd and F. G.Favaloro Jr , Name Reactions and Reagents in Organic Synthesis , Wiley-Interscience , New Jersey , 2nd edn, 2005

2. Ueber Laurent's Theorie der organischen Verbindungen

3. M. B. Smith , March's Advanced Organic Chemistry – Reactions, Mechanisms and Structure , Wiley , Hoboken, New Jersey , 2020

4. Mechanistic and Synthetic Aspects of the Benzilic Acid and Ester Rearrangements

5. P. Deslongchamps , Stereoelectronic Effects in Organic Chemistry , Pergamon Press , Oxford , 1983

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