Ruthenium(0)-catalyzed cross-coupling of aryl methyl ethers with organoboranes by selective C

Ruthenium(0)-catalyzed cross-coupling of aryl methyl ethers with organoboranes by selective C–O cleavage

Published:2023 Issue:6 Volume:10 Page:1423-1428
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Jin¹^ORCID,Wang Xin¹,Liu Jiale¹,Wang Xiaogang¹,Yang Xinkan¹,Zhao Qun²,Ma Yangmin¹,Fang Ran¹^ORCID,Szostak Michal²^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Youth Innovation Team of Shaanxi Universities and Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China

2. Department of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, USA

Abstract

A mild Ru(0)-catalyzed cleavage of C(aryl)–O bonds enabled by a combination of a Ru3(CO)12 catalyst and an imine auxiliary is reported.

Funder

Education Department of Shaanxi Province

Natural Science Basic Research Program of Shaanxi Province

China Scholarship Council

National Natural Science Foundation of China

American Chemical Society Petroleum Research Fund

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00042G

Reference46 articles.

1. Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

2. Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

3. Iron-Catalyzed C−O Bond Activation: Opportunity for Sustainable Catalysis

4. Activation of C–O and C–N Bonds Using Non-Precious-Metal Catalysis

5. Palladium-catalyzed cross-couplings by C–O bond activation