Charge transfer in mixed and segregated stacks of tetrathiafulvalene, tetrathianaphthalene and naphthalene diimide: a structural, spectroscopic and computational study

Author:

Leong Chanel F.1,Chan Bun2ORCID,Liu Tianfu3ORCID,Moore Harrison S.1,Hod Idan4ORCID,Solomon Marcello B.1ORCID,Usov Pavel M.1,Hupp Joseph T.3ORCID,Farha Omar3ORCID,D’Alessandro Deanna M.1ORCID

Affiliation:

1. School of Chemistry, The University of Sydney, New South Wales 2006, Australia

2. Graduate School of Engineering, Nagasaki University, Bunkyo 1-14, Nagasaki 852-8521, Japan

3. Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA

4. Department of Chemistry and Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev Beer-Sheva, 8410501, Israel

Abstract

We report the synthesis of novel charge transfer complexes consisting of TTF or TTN, and DPNI. A spectroscopic and computational approach is taken to elucidate charge transfer in these complexes.

Funder

U.S. Department of Energy

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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