Deconstructive di-functionalization of unstrained, benzo cyclic amines by C–N bond cleavage using a recyclable tungsten catalyst-Reference-Cited by-同舟云学术

Deconstructive di-functionalization of unstrained, benzo cyclic amines by C–N bond cleavage using a recyclable tungsten catalyst

Published:2019 Issue:20 Volume:17 Page:4970-4974
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Yujing¹²³⁴⁵,Sun Shuai⁶⁷⁸,Su Yijin¹²³⁴⁵^ORCID,Zhao Jian⁶⁷⁸,Li Yong-Hong⁶⁷⁸,Han Bo¹²³⁴⁵,Shi Feng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation

2. Lanzhou Institute of Chemical Physics (LICP)

3. Chinese Academy of Sciences

4. Lanzhou

5. P. R. China

6. University of Chinese Academy of Sciences

7. Beijing

8. China

Abstract

With H₂WO₄ as the catalyst and H₂O₂ as the oxidant, we herein report a deconstructive difunctionalization of the C–N bond in unstrained, benzo cyclic amines to generate an ester group and nitro group simultaneously.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Chinese Academy of Sciences

State Key Laboratory for Oxo Synthesis and Selective Oxidation

Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00693A

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