Uncovering the crystallography and formation mechanism of nanoscale clusters in Sb-rich SPPs of a p-type (Bi, Sb)2Te3 alloy

Author:

Ren Jie12,Wang Qichen12,Han Fuzhou12,Guo Wenbin3,Cao Yi3,Li Songbin3,Li Geping12ORCID,Ali Muhammad12ORCID,Hu Jianan12

Affiliation:

1. School of Materials Science and Engineering, University of Science and Technology of China, 96 JinZhai Road, Baohe District, Hefei, Anhui 230026, People's Republic of China

2. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, People's Republic of China

3. Jiangxi Copper Technology Research Academy Co., Ltd, Nanchang 330096, People's Republic of China

Abstract

The crystallography and formation of the Sb-rich SPPs in the (Bi, Sb)2Te3 alloy were systematically studied. When the (Bi, Sb)2Te3 alloy cooled down from the liquid state, nanosized Sb particles preferentially precipitated and aggregated, leading to the formation of Sb-rich clusters.

Publisher

Royal Society of Chemistry (RSC)

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