Isolation of OH-bridged Ag(i)/Cu(iii) and ion-pair Cu(i)/Cu(iii) trifluoromethyl complexes with monophosphines-Reference-Cited by-同舟云学术

Isolation of OH-bridged Ag(i)/Cu(iii) and ion-pair Cu(i)/Cu(iii) trifluoromethyl complexes with monophosphines

Published:2019 Issue:3 Volume:48 Page:848-853
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xiao Chang¹²³⁴⁵,Zhang Song-Lin¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Biological Colloids

2. Ministry of Education

3. School of Chemical and Material Engineering

4. Jiangnan University

5. Wuxi 214122

Abstract

An unusual Ag(i)–Cu(iii) trifluoromethyl complex is isolated and characterized, featuring linear Ag(i) and square planar Cu(iii) units that are bridged by a hydroxide ligand.

Funder

National Natural Science Foundation of China

Ministry of Education of th People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT03876G

Reference44 articles.

1. CF3-Bearing Aromatic and Heterocyclic Building Blocks

2. Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

3. Catalysis for fluorination and trifluoromethylation

4. Introduction of Fluorine and Fluorine-Containing Functional Groups

5. Aromatic Trifluoromethylation with Metal Complexes

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