Total synthesis of spiromastilactone A-Reference-Cited by-同舟云学术

Total synthesis of spiromastilactone A

Published:2019 Issue:15 Volume:17 Page:3819-3824
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Chaumont-Olive Pauline¹²³⁴⁵,Maddaluno Jacques¹²³⁴⁵^ORCID,Harrison-Marchand Anne¹²³⁴⁵^ORCID

Affiliation:

1. Normandie Université

2. UNIROUEN

3. INSA de Rouen

4. CNRS

5. Laboratoire COBRA (UMR 6014 & FR 3038)

Abstract

Spiromastilactone A is synthesized for the first time in 44% overall yield in eight synthetic steps, among which six are quantitative, and the 89 : 11 enantiomeric ratio (78% ee value) is in favour of the right enantiomer (R configuration).

Funder

Centre National de la Recherche Scientifique

Université de Rouen

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00547A

Reference25 articles.

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4. The First Total Synthesis of (±)-Napyradiomycin A1

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