Chlorination-promoted skeletal transformation of IPR C76 discovered via trifluoromethylation under the formation of non-IPR C76(CF3)nFm-Reference-Cited by-同舟云学术

Chlorination-promoted skeletal transformation of IPR C76 discovered via trifluoromethylation under the formation of non-IPR C76(CF3)nFm

Published:2018 Issue:20 Volume:47 Page:6898-6902
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tamm Nadezhda B.¹²³⁴,Brotsman Victor A.¹²³⁴,Markov Vitaliy Yu.¹²³⁴^ORCID,Kemnitz Erhard⁵⁶⁷⁸^ORCID,Troyanov Sergey I.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Moscow State University

3. 119991 Moscow

4. Russia

5. Institute of Chemistry

6. Humboldt University Berlin

7. 12489 Berlin

8. Germany

Abstract

High-temperature chlorination of IPR D₂-C₇₆ followed by trifluoromethylation resulted in X-ray structures of non-classical, non-IPR C₇₆(CF₃)₁₄, C₇₆(CF₃)₁₄F₂, and C₇₆(CF₃)₁₆F₆.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00984H

Reference32 articles.

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2. Fusing Pentagons in a Fullerene Cage by Chlorination: IPRD2-C76Rearranges into non-IPR C76Cl24

3. C76 fullerene chlorides and cage transformations. Structural and theoretical study

4. P. W. Fowler and D. E.Manolopoulos , An Atlas of Fullerenes , Clarendon , Oxford , 1995

5. Chlorination-promoted Transformation of Isolated Pentagon Rule C78 into Fused-pentagons- and Heptagons-containing Fullerenes

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