A systematic study of the influence of mesoscale structuring on the kinetics of a chemical reaction-Reference-Cited by-同舟云学术

A systematic study of the influence of mesoscale structuring on the kinetics of a chemical reaction

Published:2017 Issue:35 Volume:19 Page:23773-23780
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Krickl Sebastian¹²³⁴,Buchecker Thomas⁵²³⁴,Meyer Andreas Uwe⁶²³⁴,Grillo Isabelle⁷⁸⁹,Touraud Didier¹²³⁴,Bauduin Pierre¹⁰¹¹¹²⁹,König Burkhard⁶²³⁴^ORCID,Pfitzner Arno⁵²³⁴^ORCID,Kunz Werner¹²³⁴^ORCID

Affiliation:

1. Institute of Physical and Theoretical Chemistry

2. University of Regensburg

3. 93040 Regensburg

4. Germany

5. Institute of Inorganic Chemistry

6. Institute of Organic Chemistry

7. Institut Laue-Langevin

8. Grenoble Cedex 9

9. France

10. Institut de Chimie Séparative de Marcoule (ICSM)

11. UMR 5257 (CEA, CNRS, UM, ENSCM)

12. 30207 Bagnols-sur-Cèze

Abstract

In this contribution, we link the mesoscopic structuring of the binary structured solvent mixture H₂O/tert-butanol (TBA) to the kinetics and efficacy of the oxidation of benzyl alcohol (BA) to the corresponding aldehyde catalyzed by H₅PMo₁₀V₂O₄₀.

Funder

Verband der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Bayerisch-Französisches Hochschulzentrum

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02134H

Reference43 articles.

1. M. B. Smith and J.March, March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, John Wiley & Sons, Inc., Hoboken, New Jersey, 7th edn, 2013

2. Chemical reactivity and solution structure: on the way to a paradigm shift?

3. Solvent effects on stereoselectivity: more than just an environment

4. L. O. Kononov , Advances in Chemistry Research, Nova Science Publishers, Inc., Hauppauge, New York, 2013, vol. 18, pp. 143–177

5. Engineering biocatalytic systems in organic media with low water content

Cited by 16 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Early stages of covalent organic framework formation imaged in operando;Nature;2024-06-05

2. In-depth study of binary ethanol–triacetin mixtures in relation to their excellent solubilization power;Physical Chemistry Chemical Physics;2023

3. Polymeric Surfactant P84/Polyoxometalate α-PW12O403−—A Model System to Investigate the Interplay between Chaotropic and Hydrophobic Effects;Colloids and Interfaces;2022-03-01

4. Aggregation structure in {water + tert-butanol + benzyl alcohol} ternary solution: Measurements of density and conductivity;The Journal of Chemical Thermodynamics;2022-03

5. {2-Phases 2-reactions 1-catalyst} concept for the sustainable performance of coupled reactions;Green Chemistry;2022