Chemoselective and metal-free reduction of α,β-unsaturated ketones by in situ produced benzeneselenol from O-(tert-butyl) Se-phenyl selenocarbonate-Reference-Cited by-同舟云学术

Chemoselective and metal-free reduction of α,β-unsaturated ketones by in situ produced benzeneselenol from O-(tert-butyl) Se-phenyl selenocarbonate

Published:2020 Issue:56 Volume:10 Page:33706-33717
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Temperini Andrea¹²³⁴⁵^ORCID,Ballarotto Marco¹²³⁴⁵^ORCID,Siciliano Carlo⁶⁷⁸⁵

Affiliation:

1. Dipartimento di Scienze Farmaceutiche

2. Università di Perugia

3. Consorzio C.I.N.M.P.I.S.

4. 06123 Perugia

5. Italy

6. Dipartimento di Farmacia e Scienze della Salute e della Nutrizione

7. Università della Calabria

8. Cosenza

Abstract

The carbon–carbon double bond of arylidene acetones and chalcones can be selectively reduced with benzeneselenol generated in situ by reacting O-(tert-butyl) Se-phenyl selenocarbonate with hydrochloric acid in ethanol.

Funder

Università degli Studi di Perugia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA07128E

Reference59 articles.

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4. Organoselenium Chemistry – Synthesis and Reactions , ed. T. Wirth , Wiley WCH , Weinheim , 2011

5. Reactions of aromatic nitro, nitroso, hydroxylamino azoxy, azo and hydrazo compounds with selenol

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