Stabilization of molecular lanthanide polysulfides by bulky scorpionate ligands
Author:
Affiliation:
1. Chemisches Institut der Otto-von-Guericke-Universität
2. 39106 Magdeburg
3. Germany
4. Department of Chemistry
5. University of Alberta
6. Edmonton
7. Canada T6G 2G2
Abstract
The first well-defined lanthanide polysulfide complexes containing S42− and S52− ligands have been synthesized and structurally characterized by single-crystal X-ray diffraction.
Funder
University of Alberta
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01439A
Reference35 articles.
1. A new polymorph of Ln polysulfides (Ln = Pr and Nd)
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3. Two-dimensionally modulated structure of the rare-earth polysulfide GdS2−x (x = 0.18 ≃ 13/72)
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