Restraining the motion of a ligand for modulating the structural phase transition in two isomorphic polar coordination polymers

Author:

Wang Bao-Ying12345,Xu Wei-Jian12345,Xue Wei12345,Lin Rui-Biao12345,Du Zi-Yi12345,Zhou Dong-Dong12345,Zhang Wei-Xiong12345,Chen Xiao-Ming12345

Affiliation:

1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry

2. State Key Laboratory of Photoelectronic Materials and Technologies

3. School of Chemistry & Chemical Engineering

4. Sun Yat-Sen University

5. Guangzhou, P. R. China

Abstract

A structural phase transition induced by ligand motion was found and tuned in two new polar coordination polymers, providing a new clue for modulating phase transition behaviour in known materials.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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