Not all third-row elements experience the fluorine gauche effect: β-fluorinated organophosphorus compounds-Reference-Cited by-同舟云学术

Not all third-row elements experience the fluorine gauche effect: β-fluorinated organophosphorus compounds

Published:2017 Issue:20 Volume:41 Page:11672-11678
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Andrade Laize A. F.¹²³⁴,Freitas Matheus P.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Federal University of Lavras

3. Lavras

4. Brazil

Abstract

Conformational analyses of β-fluorinated organophosphorus compounds were theoretically carried out to probe the role of a possible fluorine–phosphorus gauche effect in conformer stabilization, specifically using a phosphine, a phosphine oxide, phosphinic and phosphonic acids, and the corresponding anions as model compounds.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ02463K

Reference33 articles.

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3. Anomeric effect plays a major role in the conformational isomerism of fluorinated pnictogen compounds

4. Conformational Analysis in Heterocyclic Systems: Recent Results and Applications

5. Origin of Fluorine/Sulfur Gauche Effect of β-Fluorinated Thiol, Sulfoxide, Sulfone, and Thionium Ion

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