Platinum(ii) alkyl complexes of chelating dibridgehead diphosphines P((CH2)n)3P (n = 14, 18, 22); facile cis/trans isomerizations interconverting gyroscope and parachute like adducts-Reference-Cited by-同舟云学术

Platinum(ii) alkyl complexes of chelating dibridgehead diphosphines P((CH2)n)3P (n = 14, 18, 22); facile cis/trans isomerizations interconverting gyroscope and parachute like adducts

Published:2021 Issue:36 Volume:50 Page:12457-12477
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhu Yun¹^ORCID,Ehnbom Andreas¹^ORCID,Fiedler Tobias¹,Shu Yi¹,Bhuvanesh Nattamai¹,Hall Michael B.¹^ORCID,Gladysz John A.¹^ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, PO Box 30012, College Station, Texas 77842-3012, USA

Abstract

The dibridgehead diphosphines P((CH2)n)3P can serve either as cis or trans spanning chelate ligands. Reactions of trans PtCl2 adducts and RLi (2 equiv.) give only cis PtR2 adducts, which upon reaction with HCl (1 equiv.) revert to trans PtRCl adducts.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02321G

Reference59 articles.

1. Artificial Molecular Rotors

2. Design of Collective Motions from Synthetic Molecular Switches, Rotors, and Motors

3. Gyroscopes and the Chemical Literature, 2002–2020: Approaches to a Nascent Family of Molecular Devices

4. Gyroscope-Like Molecules Consisting of PdX2/PtX2Rotators within Three-Spoke Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties

5. Mono- and disubstitution reactions of gyroscope like complexes derived from Cl Pt Cl rotators within cage like dibridgehead diphosphine ligands

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A tetraanionic diphosphine borate ligand: Complexation with platinum;Polyhedron;2024-05

2. Gyroscope-like platinum(IV) complexes of the macrocyclic dibridgehead diphosphine P((CH2)14)3P;Journal of Organometallic Chemistry;2023-09

3. Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)₂(I) Rotators and Cage-like Trans Aliphatic Dibridgehead Diphosphine Stators;Organometallics;2022-02-21

4. Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out;Chemical Science;2022