Fluxionality by quantum tunnelling: nonclassical 21-homododecahedryl cation rearrangement re-revisited-Reference-Cited by-同舟云学术

Fluxionality by quantum tunnelling: nonclassical 21-homododecahedryl cation rearrangement re-revisited

Published:2021 Issue:82 Volume:57 Page:10735-10738
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kozuch Sebastian¹^ORCID,Karton Amir²^ORCID,Jalife Said³,Merino Gabriel³^ORCID

Affiliation:

1. Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva 841051, Israel

2. School of Molecular Sciences, The University of Western Australia, Perth, WA 6009, Australia

3. Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, 97310, Mérida, Yucatán, Mexico

Abstract

The 21-homododecahedryl cation is a unique system in terms of its fluxionality based on two different rearrangements. We report the quantum tunneling effects that drive the reactions at temperatures where the semi-classical kinetics are impossible.

Funder

Israel Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04036G

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