Impact of donor halogenation on reorganization energies and voltage losses in bulk-heterojunction solar cells

Author:

Wu Hongbo1,Ma Zaifei1ORCID,Li Mengyang1,Lu Hao2,Tang Ailing3ORCID,Zhou Erjun3ORCID,Wen Jin1,Sun Yanming4ORCID,Tress Wolfgang5,Olsen Jógvan Magnus Haugaard6ORCID,Meloni Simone7,Bo Zhishan2ORCID,Tang Zheng1ORCID

Affiliation:

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Materials Science and Engineering, Donghua University, 201620 Shanghai, P. R. China

2. Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, 100875, Beijing, P. R. China

3. CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology, 100190 Beijing, P. R. China

4. School of Chemistry, Beihang University, 100191 Beijing, P. R. China

5. Institute of Computational Physics, Zurich University of Applied Sciences, Wildbachstr. 21, 8401 Winterthur, Switzerland

6. DTU Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark

7. Dipartimento di Scienze Chimiche, Farmaceutiche e Agrarie – DOCPAS, University of Ferrara, Ferrara, Italy

Abstract

The introduction of halogen atoms in the donor molecules in organic solar cells leads to a decrease in the reorganization energy, which in turn results in reduced non-radiative voltage losses and an improved open-circuit voltage in the devices.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanghai

Fundamental Research Funds for the Central Universities

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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