Mechanism of intramolecular transformations of nickel phosphanido hydride complexes
Author:
Affiliation:
1. A.E. Arbuzov Institute of Organic and Physical Chemistry of the Russian Academy of Sciences
2. Kazan
3. Russia
Abstract
Intramolecular interconversion of nickel phosphanido hydride complexes ([NiH{P(Ar)(H)}(dtbpe)]) occurred in three steps: first, hydride proton migrates to phosphorus, then P-Aryl moiety rotates around the P–Ni bond and finally the back migration of one proton to Ni.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02604K
Reference29 articles.
1. Palladium-Catalyzed Hydrophosphorylation of Alkynes via Oxidative Addition of HP(O)(OR)2
2. Platinum-Catalyzed Acrylonitrile Hydrophosphination via Olefin Insertion into a Pt−P Bond
3. Pt(Me-Duphos)-Catalyzed Asymmetric Hydrophosphination of Activated Olefins: Enantioselective Synthesis of Chiral Phosphines
4. Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands
5. Monomeric Phosphido and Phosphinidene Complexes of Nickel
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