Nickel-substituted zeolitic imidazolate frameworks for time-resolved alcohol sensing and photocatalysis under visible light
Author:
Affiliation:
1. Key Laboratory of Cluster Science
2. Ministry of Education of China
3. School of Chemistry
4. Beijing Institute of Technology
5. Beijing, P.R. China
6. College of Chemistry and Molecular Engineering
7. Peking University
Abstract
A facile strategy has been developed to introduce six-coordinated nickel clusters to zinc-based ZIF-8 structure via a one-pot mechanochemical synthesis. This Ni-substituted ZIF-8 can selectively pick different alcohol molecules and undergo a de-coordination to form stable four-coordinated Ni clusters which shows exceptional photo-catalytic activity.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/TA/C3TA15058E
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