Energy and temperature dependence of rigid unit modes in AlPO4-5
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra
4. Australia
5. The Bragg Institute
6. School of Chemistry
7. The University of Sydney
8. Sydney
9. Australian Nuclear Science and Technology Organisation
10. Kirrawee DC
Abstract
Rigid unit modes are shown to be dynamic within the AlPO4-5 structure down to low temperatures where the static time-averaged structure cannot provide a true physical solution.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01723H
Reference39 articles.
1. Rigid unit modes in framework silicates
2. Rigid-unit phonon modes and structural phase transitions in framework silicates
3. Rigid unit modes in crystal structures with octahedrally coordinated atoms
4. An electron diffraction study of the polymorphs of siO2-tridymite
5. An analytical solution for the zero frequency hyperbolic RUM modes of distortion of SiO2-tridymite
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