Soft interactions with hard Lewis acids: generation of mono- and dicationic alkaline-earth metal arene-complexes by direct oxidation-Reference-Cited by-同舟云学术

Soft interactions with hard Lewis acids: generation of mono- and dicationic alkaline-earth metal arene-complexes by direct oxidation

Published:2020 Issue:8 Volume:11 Page:2068-2076
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schorpp Marcel¹²³⁴⁵^ORCID,Krossing Ingo¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Freiburger Materialforschungszentrum (FMF)

3. Universität Freiburg

4. 79104 Freiburg

5. Germany

Abstract

The alkaline earths like it hard and soft! By employing a radical cationic ligand-forming oxidising agent we gained access to unprecedented mono and dicationic arene complexes of calcium, strontium and barium.

Funder

Albert-Ludwigs-Universität Freiburg

Deutsche Forschungsgemeinschaft

Carl-Zeiss-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC06254H

Reference60 articles.

1. Metallorganische Verbindungen XXI: Metallverbindungen des Cyclopentadiens

2. Unsaturated organometallic compounds of the main group elements. Dicyclopentadienylcalcium

3. The π Complexation of Alkali and Alkaline Earth Ions by the Use ofmeso-Octaalkylporphyrinogen and Aromatic Hydrocarbons

4. Dimorphic (Ba[GaCl4]2)3·2C6H6: a case of coordination extremes

5. Bulky cationic β-diketiminate magnesium complexes

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