Aromatic alkyne insertion into six-membered cyclometalated pyridine complexes of iridium: different insertion modes and structurally novel products
Author:
Affiliation:
1. Tianjin Key Laboratory of Structure and Performance for Functional Molecules
2. Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry
3. Ministry of Education
4. College of Chemistry
5. Tianjin Normal University
Abstract
Insertion reactions of aromatic alkynes into the Ir–C bond of six-membered cycloiridated complexes formed various novel products via different insertion modes.
Funder
National Natural Science Foundation of China
University of Tianjin
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA13547E
Reference51 articles.
1. N-Doped Cationic PAHs by Rh(III)-Catalyzed Double C–H Activation and Annulation of 2-Arylbenzimidazoles with Alkynes
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3. Synthesis of Mesoionic Isoquinolines by Rhodium(III)-Catalyzed C−H Activation
4. High-Valent Pentamethylcyclopentadienylcobalt(III) or -iridium(III)-Catalyzed CH Annulation with Alkynes: Synthesis of Heterocyclic Quaternary Ammonium Salts
5. Synthesis of Isoquinolinium via Rhodium(III)-Catalyzed Oxidative Annulation between Aldimines and Alkynes
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