High yield selective electrochemical conversion of N2 to NH3via morphology controlled silver phosphate under ambient conditions

Author:

Gupta Divyani1,Kafle Alankar1,Kaur Sukhjot1,Mohanty Prajna Parimita23,Das Tisita3,Chakraborty Sudip3ORCID,Ahuja Rajeev24ORCID,Nagaiah Tharamani C.1ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, Ropar, Rupnagar, Punjab 140001, India

2. Department of Physics, Indian Institute of Technology, Ropar, Rupnagar, Punjab 140001, India

3. Materials Theory for Energy Scavenging (MATES) Lab, Harish-Chandra Research Institute (HRI) Allahabad, HBNI, Chhatnag Road, Jhunsi, Prayagraj (Allahabad), 211019, India

4. Condensed Matter Theory Group, Department of Physics and Astronomy, Uppsala University, Uppsala, SE-75120, Sweden

Abstract

Ag3PO4 having cuboidal morphology is shown to have a superior activity and stability towards the electrochemical nitrogen reduction reaction for ammonia production by effectually suppressing the HER.

Funder

Science and Engineering Research Board

Vetenskapsrådet

Council of Scientific and Industrial Research, India

Department of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference65 articles.

1. Nitrogen Cycle Electrocatalysis

2. Beyond fossil fuel–driven nitrogen transformations

3. Nitrogenase Bioelectrocatalysis: From Understanding Electron-Transfer Mechanisms to Energy Applications

4. J.Nørskov , J.Chen , R.Miranda , T.Fitzsimmons and R.Stack , Sustainable Ammonia Synthesis–Exploring the Scientific Challenges Associated with Discovering Alternative, Sustainable Processes for Ammonia Production , US DOE Office of Science , 2016

5. A comparison of the chemical, optical and electrocatalytic properties of water-oxidation catalysts for use in integrated solar-fuel generators

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