On the nature of the electronic effect of multiple hydroxyl groups in the 6-membered ring – the effects are additive but steric hindrance plays a role too-Reference-Cited by-同舟云学术

On the nature of the electronic effect of multiple hydroxyl groups in the 6-membered ring – the effects are additive but steric hindrance plays a role too

Published:2017 Issue:5 Volume:15 Page:1164-1173
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Pedersen Christian Marcus¹²³⁴^ORCID,Bols Mikael¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Copenhagen

3. 2100 Copenhagen Ø

4. Denmark

Abstract

Electronic and steric effects each play important roles in determining the base strength in piperidines.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C6OB02427K

Reference36 articles.

1. Some Relations between Reaction Rates and Equilibrium Constants.

2. A Precise Correlation of Nuclear Magnetic Shielding in m- and p-Substituted Fluorobenzenes by Inductive and Resonance Parameters from Reactivity

3. Prediction of the strengths of organic bases

4. On the Prediction of pK_a Values of Amino Sugars

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