Optical phonons in the kesterite Cu2ZnGeS4 semiconductor: polarized Raman spectroscopy and first-principle calculations

Author:

Guc M.12345,Litvinchuk A. P.6789,Levcenko S.101112,Valakh M. Ya.13141516,Bodnar I. V.17181920,Dzhagan V. M.1314151621,Izquierdo-Roca V.1234,Arushanov E.5222324,Pérez-Rodríguez A.123425

Affiliation:

1. IREC

2. Catalonia Institute for Energy Research

3. Sant Adria del Besos

4. Spain

5. Institute of Applied Physics

6. Texas Center for Superconductivity and Department of Physics

7. University of Houston

8. Houston

9. USA

10. Helmholtz Zentrum Berlin fur Materialien und Energie

11. Berlin D-14109

12. Germany

13. Institute of Semiconductor Physics

14. National Academy of Sciences of Ukraine

15. Kiev 03028

16. Ukraine

17. Department of Chemistry

18. Belarusian State University of Informatics and Radioelectronics

19. Minsk

20. Belarus

21. Semiconductor Physics

22. Academy of Sciences of Moldova

23. Chisinau MD 2028

24. Moldova

25. IN2UB

Abstract

A comprehensive vibrational analysis of the kesterite Cu2ZnGeS4 is reported, which includes in-plane rotation polarized Raman scattering measurements from the (1 0 1)-single crystal facet as well as first principle lattice dynamic calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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