Divergent 1,2-carboallylation of terminal alkynes enabled by metallaphotoredox catalysis with switchable triplet energy transfer-Reference-Cited by-同舟云学术

Divergent 1,2-carboallylation of terminal alkynes enabled by metallaphotoredox catalysis with switchable triplet energy transfer

Published:2023 Issue:43 Volume:14 Page:12143-12151
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Qin Jian¹,Zhang Zhuzhu¹,Lu Yi¹,Zhu Shengqing¹^ORCID,Chu Lingling¹^ORCID

Affiliation:

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry and Chemical Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China

Abstract

We report a selective and stereodivergent three-component carboallylation of terminal alkynes with allylic carbonates and alkyl trifluoroborates via metallaphotoredox catalysis with pyrene as a triplet energy transfer (EnT) modulator.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC04645A

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