Bounding [AnO<sub>2</sub>]<sup>2+</sup>(An = U, Np) covalency by simulated O K-edge and An M-edge X-ray absorption near-edge spectroscopy-Reference-Cited by-同舟云学术

Bounding [AnO₂]²⁺(An = U, Np) covalency by simulated O K-edge and An M-edge X-ray absorption near-edge spectroscopy

Published:2023 Issue:35 Volume:25 Page:23753-23760
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Stanistreet-Welsh Kurtis¹^ORCID,Kerridge Andrew¹^ORCID

Affiliation:

1. Department of Chemistry, Lancaster University, Lancaster, LA1 4YB, UK

Abstract

Simulated O K-edge and an M-edge XANES data are combined to bound actinide covalency in uranyl and neptunyl, demonstrating the validity of inferring ground state bonding character from core-excited state electronic structures for these compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP03149G

Reference60 articles.

1. Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning

2. Multicoordinate ligands for actinide/lanthanide separations

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4. Catalytic insertion of E–H bonds (E = C, N, P, S) into heterocumulenes by amido–actinide complexes

5. Future Directions for Transuranic Single Molecule Magnets

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