Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis-Reference-Cited by-同舟云学术

Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis

Published:2017 Issue:6 Volume:15 Page:1321-1324
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Matsumoto Arimasa¹²³⁴⁵,Yonemitsu Kento¹²³⁴,Ozaki Hanae¹²³⁴,Míšek Jiří⁶⁷⁸⁹,Starý Ivo⁶⁷⁸⁹,Stará Irena G.⁶⁷⁸⁹,Soai Kenso¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Tokyo University of Science

3. Tokyo

4. 162-8601 Japan

5. Research Institute of Science and Technology

6. Institute of Organic Chemistry and Biochemistry

7. Czech Academy of Sciences

8. 166 10 Prague 6

9. Czech Republic

Abstract

Reversal of the sense of enantioselectivity was observed between 1-aza[6]helicene 2 and 2-aza[6]helicene 3 employed as chiral inducers of asymmetric autocatalysis of pyrimidyl alkanol.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C6OB02745H

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5. Helicenes: Synthesis and Applications

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