Bonding trends across the series of tricarbonato-actinyl anions [(AnO2)(CO3)3]4− (An = U–Cm): the plutonium turn-Reference-Cited by-同舟云学术

Bonding trends across the series of tricarbonato-actinyl anions [(AnO2)(CO3)3]4− (An = U–Cm): the plutonium turn

Author:

Liu Jian-Biao¹²³⁴⁵,Chen Guo P.⁶⁷⁸⁹,Huang Wei⁶⁷⁸⁹,Clark David L.¹⁰¹¹¹²,Schwarz W. H. Eugen⁶⁷⁸⁹¹³,Li Jun⁶⁷⁸⁹¹⁴^ORCID

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Materials Science

3. Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong

4. Shandong Normal University

5. Jinan 250014

6. Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education

7. Tsinghua University

8. Beijing 100084

9. China

10. Los Alamos National Laboratory

11. Los Alamos

12. USA

13. Physical and Theoretical Chemistry

14. Environmental Molecular Science Laboratory

Abstract

Strong variation of actinide f-orbital energy-levels with nuclear AND ionic charges lowers the highest possible oxidation-states from Pu onwards.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

Reference127 articles.

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