Effect of anions on the phase transition temperature of two structurally isomeric polymers: poly(N-isopropylacrylamide) and poly(2-isopropyl-2-oxazoline)

Author:

Chung Taehun1ORCID,Han Jihoon1ORCID,Kim Young Jae2,Jeong Kyeong-Jun2,Koo Jun Mo3ORCID,Lee Jemin4,Park Hyung Gyu4,Joo Taiha2ORCID,Kim Youn Soo15ORCID

Affiliation:

1. Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-Ro, Nam-Gu, Pohang, Gyeongbuk 37673, Republic of Korea

2. Department of Chemistry, Pohang University of Science and Technology (POSTECH), 77 Cheongam-Ro, Nam-Gu, Pohang, Gyeongbuk 37673, Republic of Korea

3. Research Center for Bio-based Chemistry, Korea Research Institute of Chemical Technology (KRICT), Ulsan 44429, Republic of Korea

4. Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-Ro, Nam-Gu, Pohang, Gyeongbuk 37673, Republic of Korea

5. Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-Ro, Nam-Gu, Pohang, Gyeongbuk 37673, Republic of Korea

Abstract

In chaotropic solution, the different lower critical solution temperature (LCST) increments of two structural isomers, namely, poly(N-isopropylacrylamide) (PNIPAAm) and poly(2-isopropyl-2-oxazoline) (PiPOx), is studied.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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