Prolonged lifespan of initial-anode-free lithium-metal battery by pre-lithiation in Li-rich Li2Ni0.5Mn1.5O4spinel cathode

Author:

Chen Leiyu1,Chiang Chao-Lung2ORCID,Wu Xiaohong1,Tang Yonglin1ORCID,Zeng Guifan1,Zhou Shiyuan1,Zhang Baodan1,Zhang Haitang1,Yan Yawen1,Liu Tingting3,Liao Hong-Gang1ORCID,Kuai Xiaoxiao14,Lin Yan-Gu2,Qiao Yu14ORCID,Sun Shi-Gang1ORCID

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, PR China

2. National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan, Republic of China

3. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China

4. Fujian Science & Technology Innovation Laboratory for Energy Materials of China (Tan Kah Kee Innovation Laboratory), Xiamen, 361005, PR China

Abstract

Benefiting from highly reversible structure evolution of pre-lithiated Li-rich Li2Ni0.5Mn1.5O4cathode, the corresponding anode-free pouch cell delivers a considerable energy density of 350 W h kg−1and 97% capacity retention after 50 cycles.

Funder

National Natural Science Foundation of China

Xiamen University

Fundamental Research Funds for the Central Universities

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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