Structure, magnetic anisotropy and relaxation behavior of seven-coordinate Co(ii) single-ion magnets perturbed by counter-anions

Author:

Yi Gangji1234,Zhang Chunyang1234,Zhao Wen1234,Cui Huihui56784,Chen Lei1234ORCID,Wang Zhenxing910114ORCID,Chen Xue-Tai56784ORCID,Yuan Aihua1234ORCID,Liu Yuan-Zhong121314415,Ouyang Zhong-Wen910114

Affiliation:

1. School of Environmental and Chemical Engineering

2. Jiangsu University of Science and Technology

3. Zhenjiang 212003

4. P. R. China

5. State Key Laboratory of Coordination Chemistry

6. School of Chemistry and Chemical Engineering

7. Nanjing University

8. Nanjing 210093

9. Wuhan National High Magnetic Field Center& School of Physics

10. Huazhong University of Science and Technology

11. Wuhan 430074

12. Suzhou Institute of Biomedical Engineering and Technology

13. Chinese Academy of Sciences

14. Suzhou 215163

15. Jinan Guoke Medical Technology Development Co.

Abstract

A series of mononuclear seven-coordinate complexes with the same coordination unit [Co(BPA-TPA)]2+ (BPA-TPA = pentapyidyldiamine) display the different slow magnetic relaxation processes perturbed by the variation of the counter anions.

Funder

National Natural Science Foundation of China

Six Talent Peaks Project in Jiangsu Province

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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