Manipulating the spin crossover behaviour in a series of cyanide-bridged {FeIII2FeII2} molecular squares through NCE<sup>−</sup> co-ligands-Reference-Cited by-同舟云学术

Manipulating the spin crossover behaviour in a series of cyanide-bridged {FeIII2FeII2} molecular squares through NCE⁻ co-ligands

Published:2022 Issue:14 Volume:51 Page:5596-5602
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

You Maolin¹²,Nguyen Giang T.²^ORCID,Shao Dong¹^ORCID,Wang Te¹,Chang Xiao-Yong¹,Ungur Liviu²^ORCID,Zhang Yuan-Zhu¹^ORCID

Affiliation:

1. Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, P. R. China

2. Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543

Abstract

Three molecular squares with tunable transition temperature (T1/2) through the substitution of NCE− (E = S, Se, BH3) anions were prepared, demonstrating another effective way to tune the SCO properties of the [FeIII–CN–FeII] systems.

Funder

Natural Science Foundation of Shenzhen City

National Natural Science Foundation of China

Southern University of Science and Technology

National University of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00058J

Reference67 articles.

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2. M. A.Halcrow , Spin-crossover materials: properties and applications , John Wiley & Sons , 2013

3. Multifunctionality in spin crossover materials

4. Manipulating Spin Transition To Achieve Switchable Multifunctions

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