A stable radical within a N–Co–N core-Reference-Cited by-同舟云学术

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A stable radical within a N–Co–N core

Published:2024 Issue:73 Volume:60 Page:9970-9973
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bhandari Anirban¹,Park Gyeong Min¹^ORCID,Lee Heui Beom¹^ORCID,Hong Sugyeong²^ORCID,Kim Sun Hee²^ORCID,Byon Hye Ryung³^ORCID,Lee Yunho¹^ORCID

Affiliation:

1. Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea

2. Western Seoul Centre, Korea Basic Science Institute, Seoul 03759, Republic of Korea

3. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

Abstract

A stable radical species of an octahedral cobalt complex reveals a delocalized spin density within a N–Co–N core. Its reversible redox interconversion was observed in the presence of an acid or a base.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02146K

Reference27 articles.

1. Metal Complexes of Aminyl Radicals

2. Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications

3. Redox-active ligands in catalysis

4. Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis

5. Persistent and Stable Organic Radicals: Design, Synthesis, and Applications

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