Lowering water oxidation overpotentials using the ionisable imidazole of copper(2-(2′-pyridyl)imidazole)-Reference-Cited by-同舟云学术

Lowering water oxidation overpotentials using the ionisable imidazole of copper(2-(2′-pyridyl)imidazole)

Published:2017 Issue:3 Volume:53 Page:651-654
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Stott Leea A.¹²³⁴⁵,Prosser Kathleen E.¹²³⁴⁵,Berdichevsky Ellan K.¹²³⁴⁵,Walsby Charles J.¹²³⁴⁵,Warren Jeffrey J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Simon Fraser University

3. 8888 University Drive

4. Burnaby BC V5A 1S6

5. Canada

Abstract

Rapid and low overpotential oxidation of water to dioxygen remains a key hurdle for storage of solar energy. Deprotonation of an ionisable imidazole ligand in homogeneous copper catalysts lower overpotentials.

Funder

Natural Sciences and Engineering Research Council of Canada

Canadian Institute for Advanced Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC09208J

Reference42 articles.

1. Molecular Catalysts for Water Oxidation

2. Powering the planet: Chemical challenges in solar energy utilization

3. Homogeneous water oxidation catalysts containing a single metal site

4. A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II

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