Synthesis, structure and properties of new bimetallic sodium and potassium lanthanum borohydrides

Author:

Payandeh GharibDoust SeyedHosein1234,Heere Michael5678,Sørby Magnus H.5678,Ley Morten B.91011,Ravnsbæk Dorthe B.121314154,Hauback Bjørn C.5678,Černý Radovan1617181920,Jensen Torben R.1234ORCID

Affiliation:

1. Department of Chemistry and Interdisciplinary Nanoscience Center (iNANO)

2. Aarhus University

3. 8000 Aarhus C

4. Denmark

5. Physics Department

6. Institute for Energy Technology

7. NO-2027 Kjeller

8. Norway

9. Max-Planck-Institut für Kohlenforschung

10. 45470 Mülheim an der Ruhr

11. Germany

12. Department of Physics

13. Chemistry and Pharmacy

14. University of Southern Denmark (SDU)

15. 5320 Odense M

16. Laboratory of Crystallography

17. Department of Quantum Matter Physics

18. University of Geneva, Quai Ernest-Ansermet 24

19. Geneva

20. Switzerland

Abstract

New compounds, NaLa(BH4)4 and K3La(BH4)6, are synthesized. NaLa(BH4)4 has a new structure type and has partial reversibility for hydrogen release.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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