Electroclinic effect in a chiral carbosilane-terminated 5-phenylpyrimidine liquid crystal with ‘de Vries-like’ properties

Author:

Schubert Christopher P. J.1234,Müller Carsten5678,Wand Michael D.9101112,Giesselmann Frank5678,Lemieux Robert P.1234

Affiliation:

1. Chemistry Department

2. Queen's University

3. Kingston

4. Canada

5. Institute of Physical Chemistry

6. University of Stuttgart

7. D-70569 Stuttgart

8. Germany

9. LC Vision

10. LLC

11. Boulder

12. USA

Abstract

The chiral carbosilane-terminated liquid crystal 2-[(2S,3S)-2,3-difluorohexyloxy]-5-[4-(12,12,14,14,16,16-hexamethyl-12,14,16-trisilaheptadecyloxy)phenyl]pyrimidine (QL32-6) undergoes a smectic A*-smectic C* phase transition with a maximum layer contraction of only 0.2%.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference36 articles.

1. C. Bahr , in Chirality in Liquid Crystals, ed. H.-S. Kitzerow and C. Bahr, Springer-Verlag, New York, 2001, p. 223

2. N. A. Clark and S. T.Lagerwall, in Ferroelectric Liquid Crystals: Principles, Properties and Applications, ed. J. W. Goodby, R. Blinc, N. A. Clark, S. T. Lagerwall, M. A. Osipov, S. A. Pikin, T. Sakurai, K. Yoshino and B. Zeks, Gordon & Breach, Philadelphia, 1991, p. 84

3. Simple Molecular Model for the SmecticAPhase of Liquid Crystals

4. Electroclinic Effect at theA−CPhase Change in a Chiral Smectic Liquid Crystal

5. Switching behaviour and electro-optic response due to the soft mode ferroelectric effect in chiral smectic A liquid crystals

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