The atmospheric oxidation of CH3OOH by the OH radical: the effect of water vapor

Author:

Anglada Josep M.123ORCID,Crehuet Ramon123ORCID,Martins-Costa Marilia45678,Francisco Joseph S.9101112,Ruiz-López Manuel45678

Affiliation:

1. Departament de Química Biològica i Modelització Molecular (IQAC – CSIC)

2. E-08034 Barcelona

3. Spain

4. SRSMC

5. University of Lorraine

6. CNRS

7. 54506 Vandoeuvre-lès-Nancy

8. France

9. College of Arts and Sciences

10. University of Nebraska-Lincoln

11. 1223 Oldfather Hall Lincoln

12. USA

Abstract

The relative humidity can enhance the atmospheric oxidation of CH3OOH by OH into CH3O2 + H2O up to 19% whereas the formation of H2CO + OH + H2O is enhanced up to 5% only under the same conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference64 articles.

1. Atmospheric chemistry of VOCs and NOx

2. D. J. Jacob , in Handbook of Weather, Climate and Water: Atmospheric Chemistry, Hydrology and Societal Impacts, ed. T. D. Potter and B. R. Colman, Wiley-Interscience, Hoboken, New Jersey, 2003

3. B. Finlayson-Pitts and J. J.Pitts, Chemistry of the Upper and Lower Atmosphere. Theory, Experiments, and Applications, Academic Press, San Diego, 2000

4. Atmospheric chemistry of small organic peroxy radicals

5. Mechanistic Study of the CH3O2• + HO2• → CH3O2H + O2 Reaction in the Gas Phase. Computational Evidence for the Formation of a Hydrogen-Bonded Diradical Complex

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