Regiodivergent synthesis of pyrazino-indolines vs. triazocines via α-imino carbenes addition to imidazolidines-Reference-Cited by-同舟云学术

Regiodivergent synthesis of pyrazino-indolines vs. triazocines via α-imino carbenes addition to imidazolidines

Published:2021 Issue:4 Volume:12 Page:1479-1485
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guarnieri-Ibáñez Alejandro¹²³,de Aguirre Adiran¹²³^ORCID,Besnard Céline⁴²³^ORCID,Poblador-Bahamonde Amalia I.¹²³^ORCID,Lacour Jérôme¹²³^ORCID

Affiliation:

1. Department of Organic Chemistry

2. University of Geneva

3. Switzerland

4. Laboratory of Crystallography

Abstract

Hexahydropyrazinoindoles are prepared in a single step from N-sulfonyl triazoles and imidazolidines. Of mechanistic importance, a regiodivergent reactivity can be engineered towards the exclusive formation of 8-membered ring 1,3,6-triazocines.

Funder

Université de Genève

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05725H

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