4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: the silver role-Reference-Cited by-同舟云学术

4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: the silver role

Published:2019 Issue:28 Volume:48 Page:10412-10416
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Conejo-Rodríguez Verónica¹²³⁴⁵^ORCID,Peñas-Defrutos Marconi N.¹²³⁴⁵^ORCID,Espinet Pablo¹²³⁴⁵^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica

2. Facultad de Ciencias

3. Universidad de Valladolid

4. 47071-Valladolid

5. Spain

Abstract

X-Ray and DFT studies support that the red-shift of luminescence from [AuAr(CNPy-4)] (Ar = C₆F₅, C₆F₃Cl₂-3,5) to [Ag[AuAr(CNPy-4)]₂](BF₄) is not due to non-existent Au⋯Ag interactions but to adoption of structures with shorter Au⋯Au distances.

Funder

Ministerio de Economía y Competitividad

Consejería de Educación, Junta de Castilla y León

Ministerio de Educación, Cultura y Deporte

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01618J

Reference33 articles.

1. Mechanoresponsive Luminescent Molecular Assemblies: An Emerging Class of Materials