Structure and bonding in Au(i) chloride species: a critical examination of X-ray absorption spectroscopy (XAS) data

Author:

Chang Sin-Yuen12345,Uehara Akihiro12345,Booth Samuel G.12345,Ignatyev Konstantin675,Mosselmans J. Frederick W.675,Dryfe Robert A. W.12345,Schroeder Sven L. M.12345

Affiliation:

1. School of Chemical Engineering and Analytical Science

2. School of Chemistry

3. The University of Manchester

4. Manchester M13 9PL

5. UK

6. Diamond Light Source Ltd

7. Didcot

Abstract

We determined a reliable Au(i) chloride X-ray absorption spectrum from dichlorobenzene solutions containing varying amounts of [AuCl2]and [AuCl3OH].

Funder

University Of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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4. New Insights into Brust−Schiffrin Metal Nanoparticle Synthesis

5. Understanding the Microscopic Origin of Gold Nanoparticle Anisotropic Growth from Molecular Dynamics Simulations

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