Thermally cross-linkable fluorene-based hole transporting materials: synthesis, characterization, and application in perovskite solar cells

Author:

Vaitukaityte Deimante1,Magomedov Artiom12ORCID,Rakstys Kasparas1,Kwiatkowski Simon3,Kamarauskas Egidijus4,Jankauskas Vygintas4,Rousseau Jolanta3,Getautis Vytautas1ORCID

Affiliation:

1. Department of Organic Chemistry, Kaunas University of Technology, Radvilenu pl. 19, Kaunas 50254, Lithuania

2. Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO, 80309, USA

3. Univ. Artois, CNRS, Centrale Lille, Univ. Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, Faculty of Science Jean Perrin, Rue Jean Souvraz SP 18, F-62300 Lens, France

4. Institute of Chemical Physics, Vilnius University, Sauletekio al. 3, Vilnius 10257, Lithuania

Abstract

Organic semiconductors containing two vinyl groups can undergo thermal cross-linking polymerization at 214 °C leading to higher hole mobilities compared to uncross-linked films and significantly improved efficiencies of perovskite solar cells.

Funder

Lietuvos Mokslo Taryba

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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