Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp3)–H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis-Reference-Cited by-同舟云学术

Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp3)–H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis

Published:2019 Issue:12 Volume:10 Page:3459-3465
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mitsunuma Harunobu¹²³⁴^ORCID,Tanabe Shun¹²³⁴,Fuse Hiromu¹²³⁴,Ohkubo Kei⁵⁶⁷⁸⁴^ORCID,Kanai Motomu¹²³⁴^ORCID

Affiliation:

1. Graduate School of Pharmaceutical Sciences

2. The University of Tokyo

3. Tokyo 113-0033

4. Japan

5. Institute for Advanced Co-Creation Studies

6. Open and Transdisciplinary Research Initiatives

7. Osaka University

8. Osaka 565-0871

Abstract

We have developed a catalytic asymmetric nucleophilic allylation of aldehydes using simple alkenes as pronucleophiles without relying on stoichiometric metals.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05677C

Reference92 articles.

1. Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

2. Radical Enantioselective C(sp3 )−H Functionalization

3. Enantioselective C(sp 3 )‒H bond activation by chiral transition metal catalysts

4. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

Cited by 149 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Visible light–driven organic synthesis under other miscellaneous photocatalysis;Visible Light-Driven Organic Synthesis;2025

2. A novel Fe(III) and 2-amino-perimidinium based hybrid material catalyzed friedel–Crafts type hydroarylation of alkynes: Scope and mechanism;Journal of Molecular Structure;2024-10

3. Asymmetric radical allylation of β-keto esters with vinyl cyclopropanes by dual photoredox/nickel catalysis;Science China Chemistry;2024-08-27

4. Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization;Chemical Reviews;2024-08-08

5. Photoredox/Nickel Dual-Catalyzed Allylation of Aldehydes with Allylic Alcohols and Mechanistic Insights in the Presence of CO₂;ACS Catalysis;2024-08-05