Alternative ball-milling synthesis of vanadium-substituted polyoxometalates as catalysts for the aerobic cleavage of C–C and C

Alternative ball-milling synthesis of vanadium-substituted polyoxometalates as catalysts for the aerobic cleavage of C–C and C–O bonds

Published:2021 Issue:37 Volume:50 Page:12850-12859
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Al-Hussaini Louay¹²,Valange Sabine³,Gálvez Maria Elena²^ORCID,Launay Franck¹^ORCID

Affiliation:

1. Sorbonne Université, CNRS, UMR 7197, Laboratoire de Réactivité de Surface (LRS), F-75005 Paris, France

2. Sorbonne Université, CNRS, UMR 7190, Institut Jean le Rond d'Alembert, F-75005 Paris, France

3. Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), Université de Poitiers, CNRS, ENSI Poitiers, B1, 1 rue Marcel Doré, F-86073 Poitiers Cedex 9, France

Abstract

Ball-milling-based synthesis of vanadium-substituted phosphomolybdic acid enables energy saving while improving the yield and providing active catalysts for aerobic oxidative cleavage.

Funder

Sorbonne Université

European Regional Development Fund

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01585K

Reference56 articles.

1. Dioxygen in Polyoxometalate Mediated Reactions

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3. Alternatives for lignocellulosic pulp delignification using polyoxometalates and oxygen: a review

4. Vanadium-Substituted Phosphomolybdic Acids for the Aerobic Cleavage of Lignin Models—Mechanistic Aspect and Extension to Lignin

5. Catalytic oxidation of lignin to valuable biomass-based platform chemicals: A review

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