Paired electrolysis enables weak Brønsted base-promoted amination of arenes with N,N-dialkyl formamides as the amine source

Author:

Ye Xiao-Xia1,Liu Min1,Wang Shi-Yan1,Zheng Jin-Ming1,Li Yi-Fei1,Yan Meng-Xiao2,Hu Xiao-Dong3,Luo Yan-Shu2,Zeng You-Yun3,Cai Yun-Rui1ORCID,Li Ren-Hao1ORCID

Affiliation:

1. State Key Laboratory of Macromolecular Drugs and Large-Scale Manufacturing, School of Pharmaceutical Sciences, Wenzhou Medical University, Wenzhou 325035, China

2. College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325035, China

3. School and Hospital of Stomatology, Wenzhou Medical University, Wenzhou 325035, China

Abstract

A paired electrolysis enabled amination of arenes using N,N-dialkyl formamides as the amine source for the synthesis of arylamines without the need for chemical oxidants, metal catalysts or high temperatures is reported.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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