Coordination chemistry effects of the space-demanding solvent molecule N,N′-dimethylpropyleneurea

Author:

Lundberg Daniel1ORCID,Lindqvist-Reis Patric2ORCID,Łyczko Krzysztof3ORCID,Eriksson Lars4ORCID,Persson Ingmar1ORCID

Affiliation:

1. Department of Molecular Sciences, Swedish University of Agricultural Sciences, P.O.Box 7015, SE-750 07 Uppsala, Sweden

2. European Spallation Source ERIC, P.O.Box 176, SE-221 00 Lund, Sweden

3. Institute of Nuclear Chemistry and Technology, Dorodna 16, PL-03-195 Warszawa, Poland

4. Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden

Abstract

The coordination chemistry of N,N′-dimethylpropyleneurea (dmpu) coordinated metal ions and complexes is reviewed. Dmpu is space-demanding at coordination forcing most metal ions and complexes to adopt lower coordination numbers than in most cases.

Funder

Vetenskapsrådet

U.S. Department of Energy

National Institute of General Medical Sciences

Lunds Universitet

Knut och Alice Wallenbergs Stiftelse

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference52 articles.

1. J. A.Riddick and W. B.Bunger , Techniques of Chemistry, Organic Solvents , Wiley-Interscience , New York , 1970 , vol. II

2. Y.Marcus , The Properties of Solvents , John Wiley & Sons , Chichester , 1998 , ISBN: 978-0-471-98369-9

3. Substitution of HMPT by the cyclic urea DMPU as a cosolvent for highly reactive nucleophiles and bases

4. Chemistry of organosilicon compounds

5. Harnstoffe als Lösungsmittel in der chemischen Forschung

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